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CAS No.:110-19-0

Name: Isobutyl acetate

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Details Introduction

TOXICITY DATA with REFERENCE:

1.    

skn-rbt 500 mg open MLD

    UCDS**    Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 11/3 ,1971.
2.    

skn-rbt 500 mg/24H MOD

    FCTXAV    Food and Cosmetics Toxicology. 16 (1978),637.
3.    

eye-rbt 500 mg/24H MOD

    FCTXAV    Food and Cosmetics Toxicology. 16 (1978),637.
4.    

orl-rat LD50:13,400 mg/kg

    NPIRI*    Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. 1 (1974),8.
5.    

ihl-rat LCLo:8000 ppm/4H

    AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),95.
6.    

orl-rbt LD50:4763 mg/kg

    IMSUAI    Industrial Medicine and Surgery. 41 (1972),31.

Consensus Reports:

Reported in EPA TSCA Inventory.


SAFETY PROFILE:

Mildly toxic by ingestion and inhalation. A skin and eye irritant. Upon absorption by the body it can hydrolyze to acetic acid and isobutanol. Highly flammable liquid. A very dangerous fire and moderate explosion hazard when exposed to heat, flame, or oxidizers. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and fumes. See also Esters and n-butyl acetate.
Hazard Codes: FlammableF
Risk Statements: 11-66
R11:Highly flammable. 
R66:Repeated exposure may cause skin dryness or cracking.
Safety Statements: 16-23-25-29-33
S16:Keep away from sources of ignition. 
S23:Do not breathe vapour. 
S25:Avoid contact with eyes. 
S29:Do not empty into drains. 
S33:Take precautionary measures against static discharges.
RIDADR: UN 1213 3/PG 2
WGK Germany: 1
RTECS: AI4025000
HazardClass: 3
PackingGroup: II


Standards and Recommendations:

OSHA PEL: TWA 150 ppm
ACGIH TLV: TWA 150 ppm
DFG MAK: 100 ppm (480 mg/m3)
DOT Classification:  3; Label: Flammable Liquid


Analytical Methods:

For occupational chemical analysis use NIOSH: Esters I, 1450.


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